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Is it possible to map Iterative MS/MS spectra to MS1-extracted features without independent MS2 peak picking? #767

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@g0079

Hi MS-DIAL developers,

I am currently working with untargeted metabolomics data acquired on an Agilent Q-TOF using the Iterative MS/MS (Auto MS/MS) mode.

Due to the nature of iterative acquisition, the chromatographic sampling points (points per peak) in the MS/MS runs are insufficient for reliable peak deconvolution. Furthermore, there are minor retention time (RT) drifts between the pure MS1 runs and the subsequent iterative MS/MS runs.

Therefore, I would like to perform feature extraction/deconvolution and alignment solely based on the high-quality MS1 data. For the iterative MS/MS data, I only want to treat them as a "spectrum pool"—meaning I want to skip the independent feature extraction for MS2, and simply map/assign the MS2 spectra directly into the features already defined by MS1.

Is there any specific setting, parameter combination, or workflow in MS-DIAL that can achieve this?

Thank you very much for your time and help!

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